Control of reaction rate by asymmetric two-state noise

نویسندگان

  • G. J. Schmid
  • P. Reimann
  • P. Hänggi
چکیده

We revisit the far from equilibrium escape problem across a fluctuating potential barrier that is driven by asymmetric, unbiased dichotomous noise. Our closed analytical solution for arbitrary noise strengths reveals new aspects of the so-called ‘‘resonant-activation’’ effect and leads to interesting implications regarding far from equilibrium or externally controlled chemical reaction processes. Specifically, a genuine asymmetry-induced variant of resonant activation within the constant intensity scaling scheme is discovered, and a new possibility to manipulate reaction rates and yields, as well as the balance between reactants and products, is put forward. © 1999 American Institute of Physics. @S0021-9606~99!51332-9#

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تاریخ انتشار 1999